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Visualization of Water Distribution in PEFC Short-stack

机译:PEFC短堆中水分布的可视化

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Polymer electrolyte fuel cells (PEFCs) have water management issues such as the flooding where condensate blocks the pores of the gas-diffusion-layer (GDL), and the plugging where condensate blocks the gas channels. Many researchers have studied these issues on the cathode side using a visualization technique, and have introduced the water repellency processing to the gas channel and GDL to solve these issues. We also confirmed by two-pole simultaneous image measurements that if water generated was transported from the cathode to the anode through the membrane, the flooding/plugging phenomena in the anode gas channel was caused in the comparison low humidity conditions [1]. The cell with the AB-CT configuration (the anode inlet was located at the bottom and the cathode inlet was located at the top) was able to maintain a uniform water distribution in the cell by water transportation through the membrane. Although most researchers confirmed these phenomena using a single cell, cannot confirm them in PEFC stack yet. The PEFC stack has peculiar issues such as flow rate distribution to each cell and temperature distribution in the stack. The supply flow rate to each cell of the stack is decided by the channel loss of each cell, and the temperature of the stack midrange become higher by the exothermic reaction (cell reaction). Moreover, even if only one cell of the stack decreased the cell performance, the cell performance of each cell influences other cells, and causes the performance deterioration of the stack. Therefore, the produced water distribution of the cell in the stack must be different from that of the single cell. However, the gas channel in the stack cannot be directly observed with a usual video camera like the single cell because the thickness of separator for the stack is so thin. Moreover, the resistance of the clear-walled cell (viewing entire gas channel) is elevated because this visualization cell was composed of the heater plate with the observation window and the current collector carved the gas channel. I-V performance of the clear-walled cell was lower than that of the solid-walled cell (the standard cell). For this reason, the results obtained by the clear-walled cell may not correctly express an actual phenomenon. We were able to observe the behavior of the plugging water in a practical PEFC using the visualization cell with three pinpoint windows [2]. We aim to observe the water distribution of each cell in the stack by applying this visualization technique to the PEFC short-stack.
机译:聚合物电解质燃料电池(PEFC)存在水管理问题,例如冷凝液堵塞气体扩散层(GDL)孔隙的溢流,以及冷凝液堵塞气体通道的堵塞。许多研究人员使用可视化技术在阴极侧研究了这些问题,并将防水处理引入到气体通道和GDL中以解决这些问题。我们还通过双极同步图像测量证实,如果产生的水通过膜从阴极传输到阳极,则在比较低湿度条件下会导致阳极气体通道中的溢流/堵塞现象[1]。AB-CT结构的电池(阳极入口位于底部,阴极入口位于顶部)能够通过膜中的水输送来保持电池中均匀的水分布。虽然大多数研究人员用单个细胞证实了这些现象,但还不能在PEFC堆栈中证实它们。PEFC电堆有一些特殊的问题,例如每个电池的流速分布和电堆中的温度分布。烟囱每个单元的供给流量由每个单元的通道损失决定,而烟囱中温则因放热反应(单元反应)而升高。此外,即使堆栈中只有一个单元降低了单元性能,每个单元的单元性能也会影响其他单元,并导致堆栈的性能恶化。因此,烟囱中单元的气田水分布必须不同于单个单元的气田水分布。然而,由于烟囱分离器的厚度非常薄,因此无法使用普通摄像机(如单电池)直接观察烟囱中的气体通道。此外,透明壁单元(查看整个气体通道)的电阻升高,因为该可视化单元由带观察窗的加热板和切割气体通道的集电器组成。透明壁电池的I-V性能低于实心壁电池(标准电池)。因此,由透明壁细胞获得的结果可能无法正确表达实际现象。我们能够使用带有三个精确窗口的可视化单元观察实际PEFC中堵水的行为[2]。我们的目的是通过将这种可视化技术应用于PEFC短堆来观察堆中每个细胞的水分分布。

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