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HF MEASUREMENTS INSIDE AN ALUMINIUM ELECTROLYSIS CELL

机译:铝电解槽内的HF测量

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HF emissions to the working atmosphere may still be a problem for the aluminium industry. The objective in the present work was to study how the HF evolution is distributed between feeder holes, other openings in the crust, gases diffusing through the crust, fumes from the secondary alumina residing on top of the crust etc. A movable "gas sniffer" connected to a Tunable Diode Laser was used to measure the HF concentrations at the above mentioned locations. The stationary HF level in an open flaming feeder hole was approximately 9000 ppm, when measured a few cm above the bath surface. In comparison, when the probe was positioned 5-10 cm above a crust area with good integrity, the HF concentration was in the range 5-10 ppm. The results support the notion that most of the HF evolves from open feeder holes and the tapping hole.
机译:工作氛围的HF排放可能仍然是铝业的问题。本作目前的目的是研究HF进化如何在馈线孔之间分布,地壳中的其他开口,漫射通过地壳的气体,从驻留在地壳顶部的次级氧化铝中的烟雾等。可移动的“气体嗅探器”使用连接到可调谐二极管激光器来测量上述位置处的HF浓度。当测量浴表面上方几厘米时,开口烧瓶馈线孔中的固定HF水平约为9000ppm。相比之下,当探针以良好的完整性定位5-10cm以上的地壳区域时,HF浓度为5-10ppm。结果支持大部分HF从开孔孔和挖掘孔演变的概念。

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