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Structure and optical properties of the amorphous hydrogenised carbon films modified by platinum nanoclusters

机译:由铂纳米能器改性的非晶氢化碳膜的结构和光学性质

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This work was carried out by taking into account that influence of platinum impurity on the properties of amorphous diamond-like carbon films are still poorly studied. In the present report optical properties of the amorphous diamond-like carbon films with platinum impurity (a-C:H ) are shown and discussed. The a-C:H films were deposited on quartz and silicon substrates. The films were fabricated by ion-plasma magnetron sputtering of combined polycrystalline graphite-platinum target. The process was carried out in hydrogen and argon gas mixture. The substrates temperature was held at 200o C and gas pressure in the chamber was kept at 1 Pa. The content of platinum impurity in the films was changed by alteration of platinum share in the combined target. Platinum content in the films was determinated by scanning electron microscope Quanta 200i 3D. The concentration of platinum in the films was varied from 0 to 10 at. %. Transmission electron microscopy (TEM) presents amorphousness of the films structure. Phase analysis of the surface was carried out with a usage of an atomic-force microscope (Integra Therma) and it was shown, that a-C:H films are two-phased and a-C:H films-three phased. Raman spectra of the a-C:H films was characterized for the a-C:H films.
机译:通过考虑到铂杂质对非晶金刚石状碳膜性能的影响仍然很差,进行了这项工作。在本报告中,显示并讨论了具有铂杂质(A-C:H 4)的无定形金刚石状碳膜的光学性质。沉积在石英和硅基板上的A-C:H 膜。通过组合的多晶石墨铂靶的离子等离子体磁控溅射来制造薄膜。该方法在氢气和氩气混合物中进行。在200℃下保持底物温度,并且腔室中的气体压力保持在1Pa。通过在组合靶标中的铂份额改变铂中的铂杂质的含量改变。通过扫描电子显微镜Quanta 200i 3d确定薄膜中的铂含量。薄膜中的铂的浓度从0到10变化。 %。透射电子显微镜(TEM)呈现薄膜结构的非晶性。表面分析表面分析用原子力显微镜(Integra Therma)的用途进行,并显示出A-C:H膜是双相和A-C:H膜 - 三相阶段。 A-C:H 薄膜的拉曼光谱的特征在于A-C:H薄膜。

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