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Dealing With H2S in Heavy Oil Thermal Projects

机译:处理重油热项目H2S

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摘要

There is an abundance of natural gas being discovered and produced that is slightly sour. According to a US Department of the Environment (DOE) survey that includes Canada, about 80% of current and new gas has a hydrogen sulphide (H2S) concentration of 1% or less. Of course, this must be treated to remove the H2S to meet sales gas specifications. For small scale (less than 50 – 100 kg) and large scale (greater than 20 tonne/d) of equivalent sulphur, current technologies appear reasonable. Conversely, for intermediate range (0.1 – 20 tonne/d) equivalent sulphur, current technology has proven to have high capital and/or operating costs and some processes are difficult to operate. Therefore, there is a need for an intermediate scale (0.1 to 20 tonne/d) process with lower capital and operating cost than those currently available. The applications of such a process range from the removal of H2S from acid gas at low pressure produced from the amine process to high pressure raw sour gas. There are additional challenges from sour gas associated with heavy oil thermal projects in that it is at low pressure and contains substantial C7 +. The elemental sulphur produced should be of sales grade quality such that the handling of the product can fit into the existing sulphur infrastructure and sold into existing markets. Otherwise, disposal of the product becomes costly and in some cases becomes another environmental problem. In answer to this need, Xergy Processing Inc. has developed a gas phase direct oxidation process for the above applications as well as treating heavy oil off-gas, fuel gas, power generation gas. The process has relatively low capital and operating costs and is easy to operate, with no equipment that is unfamiliar to the petroleum industry. Conversion to sulphur depends on the process configuration and pressure but ranges from 80% to 99.9+% based on lab and field data.
机译:已经发现并产生了丰富的天然气,略微酸味。根据美国的环境部(DOE)调查,包括加拿大,约80%的当前和新的气体的硫化氢(H2S)浓度为1%或更低。当然,必须对待删除H2S以满足销售气体规格。对于小刻度(小于50-100kg)和大规模(大于20吨/吨)的等效硫,目前的技术出现了合理的。相反,对于中间范围(0.1 - 20吨/吨)的等价硫,目前的技术已被证明具有高资本和/或运营成本,并且一些过程难以运行。因此,需要具有较低的资本和运营成本的中间尺度(0.1到20吨/ d)过程,而不是目前可用的过程。这种过程的应用范围从从胺过程中的低压下从酸气中除去H 2 S,从而高压原料酸气。与重油热项目相关的酸性气体存在额外的挑战,即它处于低压并含有大量C7 +。所产生的元素硫应该是销售级别的质量,使得产品的处理可以适合现有的硫基础设施并销售成现有市场。否则,产品处理成本高昂,在某些情况下成为另一个环境问题。在答案到这一需要时,Xergy加工公司已经开发了一种用于上述应用的气相直接氧化方法,以及处理重油废气,燃气,发电气体。该过程具有相对较低的资金和运营成本,易于操作,没有对石油工业不熟悉的设备。转换为硫磺取决于过程配置和压力,但基于实验室和现场数据的80%至99.9 +%。

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