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PHYSICOCHEMICAL PROPERTIES AND POSSIBLE APPLICATION OF LIQUID PRODUCTS FROM THERMAL DEGRADATION OF PLASTIC WASTE

机译:液体产品免于塑料废物热劣化的物理化学性质及其应用

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Utilisation of plastic wastes has been one of the most difficult problems that has recently appeared in dealing with wastes. The difficulties stem form a great diversity of plastics produced and their widespread use in practically all fields of industry. Consequently, a contribution of plastic waste in all kinds of wastes is very high and the packaging wastes make about 40% of all plastic waste. Recently, the production, and hence the use, of plastic packaging has significantly increased. Apart from packaging there are other sources of plastic waste. At present in Poland the use of plastics is estimated as 1 million tons a year and sooner or later they will become waste so all kinds of activities aimed at utilisation of plastic waste are extremely important. In utilisation of municipal plastic waste, the main problem is the packaging plastic waste, therefore, much attention has been paid to solving the question of its utilisation. In proposing the methods for plastic utilisation, apart from the qualitative and quantitative characterisation of the most important streams of plastic waste, the availability of particular technologies of plastics processing, possible demand for the products proposed and legal and organisational demands have been taken into regard. According to the regulations, production of energy by direct combustion is not recognised as recycling. Therefore, the use of high calorific value plastics for production of PDF (plastic derived fuels) cannot be accepted as the fulfilment of the recycling obligations. The conception proposed by us permits utilisation of different kinds of plastics, does not need expensive and difficult methods of purification and saves raw materials as a result of reintroduction to the cycle of some significant amounts of petrochemical raw materials. The method proposed is based on co-distillation of waste petroleum oils together with plastic waste, which satisfies the demands of the legal regulations of utilisation of oils and plastics. The products obtained are practically no different from the typical raw materials used for fuel composition.
机译:塑料废物的利用是最近出现在处理废物中的最困难问题之一。困难阀杆在几乎所有行业领域都产生了巨大的塑料,其广泛使用。因此,各种废物中的塑料废物的贡献非常高,包装废物占所有塑料废物的40%。最近,生产,并因此使用,塑料包装显着增加。除了包装外,还有其他塑料废物来源。目前在波兰目前,塑料的使用估计每年100万吨,迟早将变浪,因此旨在利用塑料废物的各种活动非常重要。在市政塑料废物的利用中,主要问题是包装塑料废物,因此,备受关注的是解决其利用问题。在提出塑料利用方法方面,除了最重要的塑料废物流的定性和定量表征外,还考虑了塑料加工的特定技术,可能提出的产品需求和提出的产品和组织需求。根据法规,通过直接燃烧产生能量不被认为是回收。因此,使用高热值塑料用于生产PDF(塑料衍生燃料)作为回收义务的实现。美国提出的概念允许利用不同种类的塑料,不需要昂贵而难以纯化的净化方法,并通过重新引入对一些大量石化原料的循环来节省原材料。所提出的方法是基于废石油油与塑料废物的共蒸馏,这满足了石油和塑料利用法律规定的要求。所得产品实际上没有与用于燃料组合物的典型原料不同。

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