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CATALYTIC REFORMING OF BIOMASS RAW FUEL GAS TO SYNGAS FOR FT LIQUID FUELS PRODUCTION

机译:FT液体燃料生产生物质原料燃料气体的催化重整

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The gasification of biomass to obtain a syngas provides a competitive means for clean FT (Fischer-Tropsch) liquid fuels from renewable resources. The feasibility of the process depends on the upgrading of raw fuel gas from gasifier to desired syngas. In this paper, partial oxidation reforming of biomass raw fuel gas with addition of 3-8 mol% O{sub}2 were investigated over nickel based monolith catalysts prepared by wet impregnation of NiO on the surface of cordierite. The composition of producer syngas was analyzed by gas chromatogram (GC) and gas chromatogram - mass spectrum (GC-MS). The carbon deposition on the surface of catalyst was analyzed by method of thermogravimetry. The results showed that partial oxidation reforming process had excellent performance of upgrading biomass raw fuel gas. Under the reforming temperature of 780°C, above 99% of biomass tar and other hydrocarbons in the raw fuel gas was converted into H{sub}2 and CO. Only trace lighter hydrocarbons (<1 mg/Nm{sup}3) as aerosol and 0.2 mol% CH{sub}4 were remained in the syngas. No coke deposition was detected during 108h lifetime test, which indicated that the addition of O{sub}2 can effectively prohibit the coke formation on the surface of catalyst. The H{sub}2/CO ratio of producer syngas can be adjusted from 1.2 to 2.5 with addition of steam, which was suitable to the synthesis of FT liquid fuels.
机译:生物质的气化以获得合成气,为来自可再生资源的清洁Ft(Fischer-Tropsch)液体燃料提供了竞争手段。该过程的可行性取决于从气化炉到所需合成气的原料燃料气体的升级。在本文中,部分氧化的生物质原燃料气中并加入3-8重整摩尔%-O {子} 2经由堇青石的表面上的NiO湿浸渍制备镍整体催化剂的影响。通过气相色谱(GC)和气相色谱 - 质谱(GC-MS)分析生产者合成气的组成。通过热再生法分析催化剂表面上的碳沉积。结果表明,部分氧化重整过程具有升级生物质原料燃料气体的优异性能。在780℃的重整温度下,在原始燃料气体中99%的生物质焦油和其他烃被转化为H {sub} 2和Co。只追踪更轻的碳氢化合物(<1 mg / nm {sup} 3)气溶胶和0.2mol%CH {Sub} 4仍保持在合成气中。在108h寿命试验期间没有检测到焦炭沉积,表明o {sub} 2可以有效地禁止催化剂表面上的焦炭形成。通过添加蒸汽,可以从1.2〜2.5调节生产者合成气的H {亚} 2 /共比,这适于合成FT液体燃料。

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