Thermal Analysis Kinetics of the Solid-State Reduction of Nickel Laterite Ores by Carbon

摘要

Non-isothermal multiple scanning rate analysis method was used to analyse the solid-state reduction of nickel laterite by carbon. According to the TG curves, the activation energies were calculated and the most probable mechanism functions were determined by the Malek method. The results show that the process can be divided into three stages according to the reaction degree (α): 0-40%, 40-70%, 70-100%, respectively. In the stage of 0 ≤ α ≤ 0.40, the most probable mechanism function fits the chemical reaction order function. In the stage of 0.40 ≤ α ≤ 0.70 and 0.70 ≤ α ≤ 1.0, the process may not be exactly described by one mechanism function.