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ELONGATIONAL RHEOLOGY AND MECHANICAL PROPERTIES OF BIODEGRADABLE PLA/PBSA BLENDS

机译:可生物降解PLA / PBSA混合物的伸长流变与力学性能

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Blends of poly(lactic acid) (PLA) and poly[(butylene succinate)-co-adipate] (PBSA) were prepared using a twin screw extruder. The morphology of the blends was examined using scanning electron microscopy (SEM). Elongational flow properties of the blends and pure components were studied. A strong strain hardening behavior was observed for PLA/PBSA blends, in which PBSA forms the continuous phase (PBSA wt% ≥ 50). The results of tensile test showed that even for blends containing only 10wt% PBSA, elongation at break increased significantly. By the addition of PBSA to PLA, a transition from brittle behavior (observed for pure PLA) to ductile behavior was observed.
机译:使用双螺杆挤出机制备聚(乳酸)(PLA)和聚[(丁二酸酯)-CO-己二酸酯](PBSA)的混合物。使用扫描电子显微镜(SEM)检查共混物的形态。研究了共混物和纯组分的伸长流动性。观察到PLA / PBSA共混物的强应变硬化行为,其中PBSA形成连续相(PBSA WT%≥50)。拉伸试验结果表明,即使对于仅含有10wt%PBSA的共混物,突破处的伸长率显着增加。通过向PLA添加PBSA,观察到从脆性行为(观察到纯PLA)转变为延展性行为。

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