RECENT DEVELOPMENTS OF LASER-INDUCED BREAKDOWN SPECTROSCOPYFOR REAL-TIME MEASUREMENT AND CONTROLOF MINERAL PROCESSING

摘要

The objective of this study was to demonstrate the application of Laser-Induced Breakdown Spectroscopy (LIBS) to the continuous analysis of online monitoring of Al, Mg, Ni, Mn, Si and Fe in nickel ore limonite and saprolite slurry samples. Analysis was performed on slurry samples in air at atmospheric pressure. Two pure samples of limonite and saprolite were used. Mixtures of the two samples in varying proportions were used to build calibration curves, study the influence of solid/liquid ratio, and evaluate short and long term reproducibility. The LIBS measurement of these elements is independent of the water content (from 70-85%, the range allowed by our setup). Repeatability of the measurement and long term reproducibility (from day-to-day) were below 1.2 % and 2% respectively for all the elements studied in our conditions. The results obtained showed that an industrial LIBS analyzer could provide the chemical composition of the six elements Al, Mg, Ni, Mn, Si and Fe within 1-2 minutes.