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HIGH SOLID CONTENT POLYACRYLIC LATEXES VIA EMULSION AND MINIEMULSION POLYMERISATION

机译:高固含量聚丙烯胶乳乳液通过乳液和微乳液聚合

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Typical industrial latex formulations often include from two to four principle monomers that constitute the basis of the final product along with a smaller number of functional monomers. These latter products are typically used to modify the final properties of the latex by tailoring them for specific applications, for instance to improve their adhesion on a substrate in the case of adhesives or surface coatings. While they are usually present in relatively small quantities (less than 5 % with respect to total monomer mass), functional monomers such as carboxylic acids can play a very important role in terms of property modification, as well as in the particle formation/stabilisation process and thus the reaction kinetics. In the current paper we will discuss different strategies for reaching solid contents as high as 76-77 % (v/v) in a one pot process with very low viscosity. I
机译:典型的工业乳胶制剂通常包括两至四个原理单体,其构成最终产品的基础以及较少数量的功能性单体。这些后一种产品通常用于通过针对特定应用定制它们来改变胶乳的最终性质,例如为了在粘合剂或表面涂层的情况下改善它们对基板上的粘附性。虽然它们通常以相对较少的量(相对于总单体质量小于5%),但诸如羧酸的功能性单体可以在性质改性以及颗粒形成/稳定过程中起着非常重要的作用因此反应动力学。在目前的论文中,我们将在一个粘度下讨论在一个罐过程中达到76-77%(v / v)的固体含量的不同策略。一世

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