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Effects Of Heating On The Oxygen-induced Radicals In Post-gamma Aged Ultra-high Molecular Weight Polyethylene

机译:热对γ老化后γ老化超高分子量聚乙烯氧诱导自由基的影响

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The results of this study suggest that the long-lived oxygen-induced radicals in aged UHMWPE have similar thermal stability at temperatures ≤ 125°C. Furthermore, detectable amount of radicals remain trapped in the polymer matrix after 12-hours of heating at 125°C. This radical retaining property of the aged UHMWPE could be attributed to changes in the molecular weight and crystallinity caused by high radiation dose (1000 kGy).
机译:该研究的结果表明,老化UHMWPE中的长寿命的氧诱导的自由基在温度≤125℃的温度下具有相似的热稳定性。此外,在12小时C的加热下在125℃下加热后,可检测量的基团在聚合物基质中被捕获。这种老化UHMWPE的自由基保持性能归因于由高辐射剂量(1000kGy)引起的分子量和结晶度的变化。

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