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STUDY ON RING CLEAVAGE AND ADDUCTIVE PROPERTY OF 2-(DINITROMETHYLENE)-4,5-IMIDAZOLIDINEDIONE

机译:2-(二硝基亚亚甲基)-4,5-咪唑烷酮环切割和粘连性能研究

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摘要

Ring cleavage of 2-(dinitromethylene)-4,5-imidazolidinedione (1) was achieved by methanol for the first time and the product was 1,1-diamino-2,2-dinitroethylene (FOX-7). 2, the first adduct of 1, was synthesized by the reaction of 1 with methanol in certain conditions and its structure was characterized. Physical and chemical properties of the adduct were studied. Parabanic acid was synthesized by decomposition of 1 in methanol, losing nitrogen oxides and carbon oxides.
机译:通过甲醇首次实现2-(二硝基亚甲基)-4,5-咪唑烷二酮(1)的戒指裂解,产物为1,1-二氨基-2,2-二萘丙烯(Fox-7)。如图2所示,通过在某些条件下用1与甲醇的反应合成1的第一加合物合成,其结构的特征在于。研究了加合物的物理和化学性质。通过甲醇,失去氮氧化物和碳氧化物的分解合成羟苄酸。

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