Testing Acid Generation in Cemented Paste Backfill

摘要

At the proposed Crandon Project, mill tailings would be depyritised for upland disposal. The resulting pyrite concentrate would be disposed of in the underground workings as a cement-amended paste backfill. In the long term, the underground workings would be flooded and the potential for the paste backfill to generate acid would be limited. However, while the mine is operational, there is potential for oxygen ingress to the backfill that may lead to sulfide mineral oxidation and acid generation. A series of humidity cell tests were completed to assess the potential for groundwater contamination. To assess effects of surface area on oxidation, the humidity cell tests were conducted on moulded cubes of paste backfill. The tests were terminated at different intervals, and the cubes were dissected and examined mineralogically. Various leach extraction procedures were also used to assess the progress of oxidation and secondary mineralisation within the paste backfill. The test results showed that: 1. the cement amendment significantly contributes to acid neutralisation and results in a lag in excess of one year before the onset of acidic conditions (in comparison to less than three weeks for the pyrite concentrate); 2. the depth of oxidation in the paste backfill is restricted to about 1 mm after 107 weeks of testing; and 3. secondary minerals form a distinct 'rind' at the surface of the paste backfill. The results indicate that acid generation in the backfilled stopes would be minimal. The importance of including the surface area effect in the testing (ie using moulded cubes) is clearly demonstrated.