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The upconversion mechanism of Tb/sup 3+/ complex containing N,N',N'-tris(2-hydrobenzamido) triethylamine

机译:含有N,N',N“ - 三乙胺(2-氢苯甲酰胺)三乙胺的Tb / sup 3 + /络合物的上转化机理

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摘要

Tb/sup 3+/ complex containing N,N',N"-tris(2-hydroxybenzamido) triethylamine was synthesized and its indirect upconversion sensitization luminescence was studied using two-photon excitation method. The results indicate there exist a phonon-assisted and a resonant energy transfer processes in different excitation range. Based on the result, an upconversion mechanism was proposed. Its efficiency was 1% at a pumping energy of 1.5 mJ under nanosecond pulse excitation, suggesting its potential use in display and probing.
机译:合成含有N,N',N“-Tris(2-羟基苯虫醛)三乙胺的Tb / sup 3 + /络合物,使用双光子激发方法研究了其间接上转化敏化发光。结果表明存在声子辅助和在不同激励范围内的共振能量转移过程。基于结果,提出了一种升高的机理。在纳秒脉冲激发下的泵送能量为1.5mJ的泵送能量下,其效率为1%,表明其在显示和探测中的潜在用途。

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