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Sonocatalytic Desulfurization

机译:Sonocatalytic Desulfization.

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摘要

Ultrasonic (US) irradiation of thiophene (T), benzothiophene (BT) or dibenzothiophene (DBT) dissolved in a water-methanol mixture, and in the presence of Ni/Al or Ni/Zn catalysts at 333 K and autogenous pressure, was used to produce desufurization of the aforementioned compounds. The system could be effective for T desufurization, and BT and DBT desufurization can also be produced, but to a lesser extent. The role of ultrasonic (US) irradiation is to increase reaction rate, and to change the catalysts' morphology producing a cleaner surface and smaller particle size, which increases catalyst activity and effectiveness.
机译:噻吩(US)照射噻吩(T),溶解在水 - 甲醇混合物中的苯并噻吩(BT)或二苯甲酸苯酚(DBT),以及在333k的Ni / Al或Ni / Zn催化剂存在下,进行自生压力,产生上述化合物的废水化。该系统可以对T废水化有效,并且也可以生产BT和DBT废水,但在较小程度上也可以生产。超声波(US)辐射的作用是提高反应速率,并改变产生更清洁的表面和更小的粒度的催化剂的形态,这增加了催化剂活性和有效性。

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