Anionic metal complexes, are very effectively bound by biomass types containing an abundance of amide groups. Readily available chitinous materials such as crab shells sorbed well anionic gold cyanide (AuCN_2~-), selenate (SeO_4~(2-)), chromate (CrO_4~2), and vanadate (VO_4~(3-)) at low pH. Equilibrium biosorption uptakes by acid-washed crab shells were up to 0.17 mmol Au/g (pH 3.5), 0.15 mmol Se/g (pH 3.0), 0.56 mmol Cr/g biomass (pH 2.0), 0.79 mmol V/g (pH 2.5). An increased ionic strength (IS as NaCl) suppressed the primary anion uptake as chloride ions competed for biosorbent protonated sites and higher IS reduced the activity of ions in solution.
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机译:阴离子金属配合物,通过含有丰富的酰胺基团的生物质类型非常有效地结合。易于使用的毛细管,如蟹壳吸附井阴离子金氰化物(Aucn_2〜 - ),硒酸盐(SeO_4〜(2-)),铬酸盐(CRO_4〜2),含钒酸盐(VO_4〜(3-))。酸洗蟹壳的平衡生物吸收高达0.17mmol Au / g(pH 3.5),0.15mmol SE / g(pH 3.0),0.56mmol Cr / g生物量(pH 2.0),0.79mmol v / g(pH值2.5)。增加的离子强度(如NaCl)抑制了作为生物吸附性位点竞争和更高的氯离子的主要阴离子摄取,从而降低了溶液中离子的活性。
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