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CARBON PARTICLE FORMATION AND DECAY IN TWO-STEP PYROLYSIS OF CARBON SUBOXIDE BEHIND SHOCK WAVES

机译:碳颗粒形成和衰减在冲击波后面的碳亚氧化碳的两步热解中

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The formation and decay of carbon particles following the pyrolysis of C_3O_2 was investigated behind reflected shock waves toward high temperatures. It is known that in hydrocarbon pyrolysis the temperature range for soot formation extends from about 1300 to 2200 K. That holds also for C_3O_2. Here, it could be observed that particle formation starts again above 2300 K and increases toward a maximum at around 3000 K, falling off steeply above 3450 K. This maximum is nearly as high as that of the low-temperature particle yield curve at around 1600-1700 K. At temperatures above 3450 K, the process of particle disappearance behind the reflected shock wave was observed, which seems to depend on the history of their formation behind the incident shock wave.
机译:将C_3O_2热解后的碳颗粒的形成和衰减研究在反射冲击波朝向高温后。众所周知,在烃热解中,烟灰地层的温度范围从约1300-2200k延伸。也适用于C_3O_2。这里,可以观察到,颗粒形成再次高于2300k,并且朝向大约3000k的最大值增加,陡峭地脱落以上3450k。该最大值几乎高于1600左右的低温颗粒产曲线-1700 K.在高于3450 k的温度下,观察到反射冲击波背后的颗粒消失过程,这似乎取决于他们在入射冲击波后面的形成历史。

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