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Strongly correlated cage compounds for thermoelectric applications?

机译:用于热电应用的强相关的笼子化合物?

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Both in the class of strongly correlated electron systems and in the class of cage compounds representatives with appealing thermoelectric properties exist. The former ones are characterized by large thermopower values, the latter ones show low and "glass-like" phonon thermal conductivities. The combination of both properties within a single compound, however, has proven challenging. We review some of our recent investigations on various cage compounds containing rare-earth elements as guest atoms and discuss their potential for thermoelectric applications. Strong correlation effects have been observed in a number of cage compounds containing Ce. While the thermoelectric performance of some of these is promising, further optimization will be needed to bring these materials to practical use.
机译:无论是在强烈相关的电子系统和笼中的类别中,都存在吸引热电性质的笼子化合物代表。前者的特征在于大型热电源值,后者显示出低和“玻璃状”声音导电性。然而,在单个化合物内的两种性质的组合已经证明了具有挑战性。我们审查了我们最近关于含有稀土元素作为客体原子的各种笼子化合物的研究,并讨论了它们对热电应用的潜力。已经在含有Ce的许多笼子化合物中观察到强相关效果。虽然其中一些是有前途的热电性能,但将需要进一步优化来使这些材料用于实际使用。

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