Different anhydrous potassium ion conducting polymer electrolytes have been studied: (POE)$-n$/KTFSI (trifluorosulfonimide), plasticized (POE)$-n$/KTFSI, (PEM)$-n$/KTFSI, and (POE-Acetal)$-n$/KTFSI. DSC and conductivity measurements have been used to characterize these electrolytes. Several solutions to avoid crystallization have been examined. The best conductivity has been obtained with (POE-Acetal)$-n$/KTFSI. This electrolyte exhibits good transmission in the VIS-IR region. The response time of cells using these electrolytes and Prussian blue and K$-x$/WO$-3$/ as electrodes has been measured and compared.
展开▼
机译:已经研究了不同的无水钾离子电解质:(PoE)$ - $ / ktfsi(三氟磺酰酰亚胺),塑化(PoE)$ - n $ / ktfsi,(pem)$ - n $ / ktfsi和(poe-acetal )$ - $ / ktfsi。 DSC和电导率测量已用于表征这些电解质。已经检查了几种以避免结晶的解决方案。使用(Poe-acetal)$ - N $ / KTFSI获得了最佳导电性。该电解质在VIS-IR区域中表现出良好的透射。使用这些电解质和普鲁士蓝色和K $-x $ / WO $ -3 $ /作为电极的响应时间已经测量并进行了比较。
展开▼