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Electrically confined quantum dot intersubband optoelectronic devices

机译:电限制量子点子带间光电器件

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Intersubband optoelectronic devices such as mid-infrared lasers and photodetectors that utilize the intersubband energy spacing (3–20 μm) are in great need for applications such as space based infrared imaging, thermal imaging, FTIR spectroscopy, and environmental and chemical process monitoring. However, the conventional quantum well (QW) based intersubband devices still have some fundamental limitations due to the continuous electronic spectrum in QWs. For example, Quantum Well Cascade lasers (QCLs) still face the limitations of fast depletion of the upper laser level by non-radiative LO-phonon-assisted emission as well as high optical loss, and Quantum Well Infrared Photodetectors (QWIPs) still require to work at a low temperature owing to high thermionic emission rates and they cannot detect normal incidence radiation due to polarization selection rules. These limitations can be avoided in principle by applying quantum dots (QDs) into these intersubband devices since the 3-D confinements in QDs. The idea of using QDs into cascade lasers and infrared photodetectors have been widely studied and confirmed. Different techniques such as self-assembly growth, electron-beam lithography, and applying magnetic field have been proposed to fabricate QDs. Here we will present a novel method of forming QD based on the lateral confinement on QW by electrical field as show in figure 1. The electrical field would deplete the QW into a very small region, forming a “quantum disk”. The field induced lateral confinement combined with the vertical confinement of the QW would form a three dimensional confinement. A similar idea of using a lateral electrical field to deplete and form a quantum ring has been proposed by Lorens et al. To use this idea to make QD intersubband devices, we have designed a novel device structure as shown in figure 2(a), which can be both used for cascade lasers and intersubband photodetectors. In this structure, gate contact,--insulator below the gate, and semiconductor substrate form a metal-insulator-semiconductor (MIS), and the gate forms a depletion region in the semiconductor area nearby. Therefore most electrons are confined in the nano-channel below the nano-injector contact, as shown in figure 2(b). In this nano-channel, the lateral energy confinement breaks the in-plane periodic lattice potential and collapses the energy bands into energy states just like QDs. With different gate voltages being applied, it will form different depletion widths in the QWs and thus effectively changes the size of the QDs. As shown in figure 3, using 3-D finite-element-method simulations we found that the electron energies were shifted to higher values with a more negative gate voltages applied and the quantum states were splitted by a large value that approaches ∼2kT at room temperature. The typical electron state wave functions are also shown in figure 3. To further develop the idea and put it into functional devices, design and fabrication of the intersubband cascade laser and photodetector devices are undergoing. Figure 4 shows typical Scanning Electron Microscope (SEM) cross-sectional images of QD devices we have fabricated. Work is still undergoing to finalize and characterize the devices.
机译:利用子带间能量间隔(3–20μm)的子带间光电器件(如中红外激光器和光电探测器)非常需要诸如基于空间的红外成像,热成像,FTIR光谱以及环境和化学过程监控之类的应用。然而,由于QW中的连续电子频谱,基于传统量子阱(QW)的子带间设备仍然具有一些基本的局限性。例如,量子阱级联激光器(QCL)仍然面临非辐射LO声子辅助发射以及高光损耗导致的激光水平快速耗尽的局限性,而量子阱红外光电探测器(QWIP)仍然需要满足以下要求:由于高的热电子发射率,它们可以在低温下工作,并且由于极化选择规则,它们无法检测到法向入射辐射。由于QD中的3-D限制,原则上可以通过将量子点(QD)应用于这些子带间设备来避免这些限制。将QD用于级联激光器和红外光电探测器的想法已得到广泛研究和证实。已经提出了诸如自组装生长,电子束光刻和施加磁场之类的不同技术来制造QD。在这里,我们将介绍一种基于电场在QW上的横向约束形成QD的新颖方法,如图1所示。电场会将QW耗尽到非常小的区域,从而形成“量子盘”。场致横向约束与QW的垂直约束相结合将形成三维约束。 Lorens等人提出了使用侧向电场耗尽并形成量子环的类似想法。为了使用这种思想制造QD子带间设备,我们设计了一种新颖的设备结构,如图2(a)所示,该结构可同时用于级联激光器和子带间光电探测器。在这种结构中,栅极接触,栅极下方的绝缘体和半导体衬底形成金属绝缘体半导体(MIS),并且栅极在附近的半导体区域中形成耗尽区。因此,大多数电子被限制在纳米注入器触点下方的纳米通道中,如图2(b)所示。在此纳米通道中,横向能量限制会破坏平面内的周期性晶格势,并使能带像QD一样崩溃为能态。施加不同的栅极电压后,它将在QW中形成不同的耗尽宽度,从而有效地改变了QD的尺寸。如图3所示,使用3-D有限元方法模拟,我们发现,随着施加更多的负栅极电压,电子能量被转移到更高的值,并且量子态被一个大的值分裂,该大的值在室温下接近约2kT。温度。典型的电子状态波函数也显示在图3中。为了进一步发展该思想并将其应用到功能器件中,正在进行带间级联激光器和光电检测器器件的设计和制造。图4显示了我们制造的QD器件的典型扫描电子显微镜(SEM)截面图。器件的定型和表征工作仍在进行中。

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