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ZONING IN CASSITERITE – A MULTIANALYTICAL APPROACH

机译:在CASSITERITE中进行分区-多种分析方法

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Cassiterite from a quartz-tourmaline rock at Nanjizal Bay, ca. 1 km from the Land’s End visitorcentre in Cornwall, was analysed using optical microscopy, SEM-BSE, SEM-CL, EBSD, andEPMA. Large (100 - 800 μm), euhedral grains grew simultaneously as tourmaline and quartz intolocal low-pressure zones or cavities. Cassiterite is typically observed as lining on clusters offine-grained tourmaline, which appear to have acted as the nucleation point (Figs. 1a and 1b).Coarse-grained quartz grow around cassiterite, and fine-grained, acicular tourmaline, typicallyassociated with cassiterite in SW England [1], occur as inclusions in both cassiterite and quartz. Inplane polarised light, cassiterite is colourless to light brown, with patchy zoning of darker brown.The dark brown patches are clearly linked to W-content (Figs. 2a and 2d), showing up to 6,000 μg/gin dark brown zones, and mostly below detection limit (~800 μg/g) in colourless zones.Cathodoluminescence (CL) textures reveal concentric growth zoning around the c-axis. A generalcorrelation between trace elements and cathodoluminescence zoning is not straightforward.However, a weak positive correlation between Ti and CL intensity (Figs. 2c and 2f), and a negativecorrelation between W and CL intensity can be observed (Figs. 2c and 2d). This is in disagreementwith Farmer et al. [2], who found W to be an CL activator. Particularly, the Ti-CL relationship isinconsistent, and other defects are likely to be the controlling CL activators. Nevertheless, Ti andNb follow the same concentric growth zones that can be observed in the CL maps.
机译:加利福尼亚Nanjizal湾的石英-电气石岩石中的锡石。离天涯海角游客1公里 康沃尔中心,使用光学显微镜,SEM-BSE,SEM-CL,EBSD和 EPMA。随着电气石和石英进入,大尺寸(100-800μm)的正反面晶粒同时生长 局部低压区或空腔。通常观察到锡石作为衬里的锡石 细颗粒的电气石,似乎已成为成核点(图1a和1b)。 粗粒石英围绕锡石生长,细粒状针状电气石通常 在英格兰西南部,与锡石相关的元素[1]以锡石和石英中的夹杂物形式出现。在 平面偏振光,锡石无色至浅棕色,暗褐色的斑片状区域。 深褐色斑块与W含量明显相关(图2a和2d),显示出高达6,000μg/ g 在深棕色区域中,并且大多数在无色区域中低于检测极限(〜800μg/ g)。 阴极发光(CL)纹理揭示了围绕c轴的同心生长区域。一般 痕量元素与阴极发光分区之间的相关性并不直接。 但是,Ti和CL强度之间的正相关性弱(图2c和2f),而负相关 可以观察到W和CL强度之间的相关性(图2c和2d)。这是不同意的 与法默(Farmer)等人。 [2],他发现W是CL激活剂。特别地,Ti-CL关系为 不一致,其他缺陷可能是控制CL活化剂。尽管如此,钛和 Nb遵循与CL图相同的同心生长区。

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