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Rheological Characteristics of Platy Kaolin

机译:板状高岭土的流变特性

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Platy kaolin can provide significant value in the coating of paper and paperboard. It can be used in multiple applications, and provide benefits such as TiO_2 extension, smoothness improvement, improved print gloss or ink set rates, calendering intensity reduction, and improved barrier properties. It is not a pigment that can be simply substituted for traditional hydrous kaolin without some adjustment to the coating formulation. These adjustments can be as simple as reducing solids but may require binder changes as well. The coater set up may need to be adjusted because of the unique rheological behaviors these pigments exhibit. The rheological characteristics of platy kaolin are explored here. This includes high shear and low shear viscosity, oscillatory measure of viscoelasticity and water retention measurements. An extensive analysis reveals some unique behaviors that need to be understood when utilizing these materials. The degree of shear thinning behaviors is investigated using the Ostwald de-Waele power law. The immobilization point was determined using the Dougherty-Krieger (1-4) equation and related to Weeks' (5) work on blade coater runnability. An indirect measure of particle shape and size synergy is also demonstrated using the Dougherty-Krieger equation parameters.
机译:板状高岭土可以在纸张和纸板的涂层中提供重要的价值。它可以用于多种应用中,并具有诸如TiO_2延伸,改善平滑度,提高印刷光泽度或油墨固化率,降低压延强度和改善阻隔性等优点。它不是可以简单地替代传统含水高岭土而无需对涂料配方进行一些调整的颜料。这些调整可以像减少固体一样简单,但也可能需要更改粘合剂。由于这些颜料表现出独特的流变行为,可能需要调整涂布机的设置。在此探讨了板状高岭土的流变特性。这包括高剪切和低剪切粘度,粘弹性的振荡测量和保水率测量。广泛的分析揭示了使用这些材料时需要理解的一些独特行为。使用Ostwald de-Waele幂定律研究了剪切稀化行为的程度。固定点是使用Dougherty-Krieger(1-4)方程确定的,并且与Weeks(5)在刮刀涂布机可运行性方面的工作有关。使用Dougherty-Krieger方程参数还可以间接测量颗粒形状和尺寸的协同作用。

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