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RHEOLOGICAL CHARACTERISTICS OF SURFACTANT-BASED FLUIDS - A COMPREHENSIVE STUDY

机译:基于表面活性剂的流体的流变特性-综合研究

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Surfactant-based fluids, SB fluids exhibit complex rheological behavior due to substantial structural change caused by the molecules self-assembled colloidal aggregation. Various factors affect their rheological properties. Among these factors, surfactant concentration, shear rate, temperature, and salinity are investigated. One of the most popular surfactants, Aromox® APA-T viscoelastic surfactant (VES) is examined. The study focuses on four different concentrations (1.5%, 2%, 3%, and 4%) over a shear rate ranging from 0.0526 sec~(-1) to 1944 sec~(-1) using Bohlin rheometer. For salinity effects, two brine solutions are used; 2 and 4% KCl while for temperature effects, a wide range from ambient temperature of 72℉ up to 200℉ is covered. The results show that SB fluids exhibit a complex rheological behavior due to its unique nature and the various structures form in the solution. In general, SB fluids at all concentrations exhibit a non-Newtonian pseudo-plastic shear thinning behavior. As the surfactant concentration and/or shear increases, a stronger shear thinning behavior can be seen. Increasing solution salinity promotes formation of rod-like micelles and increases its flexibility. Salinity affects micelles' growth and their rheological behavior is very sensitive to the nature and structure of the added salt. Different molecular structures are formed; spherical micelles occur first and then increased shear rate and/or salinity promotes the formation of rod-like micelles. Later, rod-like micelles are aligned in the flow direction and form a large super ordered structure of micellar bundles or aggregates called shear induced structure (SIS). Different structures implies different rheological properties. Likewise, rheology improves with increasing temperature up to 100℉. Further increase in temperature reverses the effects and viscosity decreases. However, the effects of temperature and salinity diminish at higher shear rates. Furthermore, a rheology master curve is developed to further understand the rheological behavior of SB fluids and correlate rheological properties to its microscopic structure.
机译:基于表面活性剂的流体,SB流体由于分子自组装胶体聚集引起的实质性结构变化而表现出复杂的流变行为。各种因素影响它们的流变性。在这些因素中,研究了表面活性剂浓度,剪切速率,温度和盐度。检查了最流行的表面活性剂之一,Aromox®APA-T粘弹性表面活性剂(VES)。该研究使用Bohlin流变仪研究了剪切速率介于0.0526 sec〜(-1)至1944 sec〜(-1)范围内的四种不同浓度(1.5%,2%,3%和4%)。为了获得盐度效果,使用了两种盐水溶液。 KCl浓度为2%和4%,而温度影响范围从72℉到200℉不等。结果表明,SB流体由于其独特的性质和溶液中形成的各种结构而表现出复杂的流变行为。通常,所有浓度的SB流体都表现出非牛顿拟塑性剪切稀化行为。随着表面活性剂浓度和/或剪切力的增加,可以看到更强的剪切稀化行为。溶液盐度的增加促进了棒状胶束的形成并增加了其柔韧性。盐度影响胶束的生长,其流变行为对添加盐的性质和结构非常敏感。形成不同的分子结构;球形胶束首先出现,然后增加的剪切速率和/或盐度促进了棒状胶束的形成。后来,棒状胶束沿流动方向排列并形成一个大的超有序的胶束或聚集体结构,称为剪切诱导结构(SIS)。不同的结构意味着不同的流变性质。同样,流变学随着温度升高至100°C而改善。温度的进一步升高会逆转作用,粘度降低。但是,温度和盐度的影响在较高的剪切速率下会减小。此外,还开发了流变主曲线,以进一步了解SB流体的流变行为,并将流变特性与其微观结构相关联。

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