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Magnetoelectrochemical Chirality

机译:磁电化学性儿

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Magnetoelectrodeposition (electrodeposition under magnetic fields) has potential to produce chiral structures of electrodeposits of metals and conducting polymers. This phenomenon is call as magnetoelectrochemical chirality. We performed the magnetoelectrodeposition of Ag films and employed them as modified electrodes. Such Ag film electrodes exhibited chiral recognition of the enantiomers of glucose and amino acids (cysteine and histidine) in the voltammograms of their oxidation reactions. Here we report chiral electrode behavior of the Ag and Cu films, depending on the deposition potentials, the magnetic fields and the surface oxidation conditions.
机译:磁电源(磁场下的电沉积)具有产生金属电吞和导电聚合物的手性结构。这种现象被称为磁电化学手性。我们进行了Ag膜的磁电极,并使用它们作为改性电极。这种Ag膜电极表现出对其氧化反应的伏安图中葡萄糖和氨基酸(半胱氨酸和组氨酸)的对映体的手性识别。在这里,我们报告了Ag和Cu膜的手性电极行为,这取决于沉积电位,磁场和表面氧化条件。

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