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Development and Testing of High Surface Area Iridium Anodes for Molten Oxide Electrolysis

机译:熔融氧电解用大表面积铱阳极的研制与测试

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摘要

Processing of lunar regolith into oxygen for habitat and propulsion is needed to support future space missions. Direct electrochemical reduction of molten regolith is an attractive method of processing, because no additional chemical reagents are needed. The electrochemical processing of molten oxides requires high surface area, inert anodes. Such electrodes need to be structurally robust at elevated temperatures (1400-1600°C), be resistant to thermal shock, have good electrical conductivity, be resistant to attack by molten oxide (silicate), be electrochemically stable and support high current density. Iridium with its high melting point, good oxidation resistance, superior high temperature strength and ductility is the most promising candidate for anodes in high temperature electrochemical processes. Several innovative concepts for manufacturing such anodes by electrodeposition of iridium from molten salt electrolyte (EL-Form~(TM)process) were evaluated. Iridium electrodeposition to form of complex shape components and coating was investigated. Iridium coated graphite, porous iridium structure and solid iridium anodes were fabricated. Testing of electroformed iridium anodes shows no visible degradation. The result of development, manufacturing and testing of high surface, inert iridium anodes will be presented.
机译:为了支持未来的太空飞行,需要将月球重石转变成氧气以用于栖息地和推进。因为不需要额外的化学试剂,所以直接电化学还原熔融的硬石膏是一种有吸引力的加工方法。熔融氧化物的电化学处理需要高表面积的惰性阳极。这样的电极在高温(1400-1600℃)下必须在结构上坚固,耐热冲击,具有良好的导电性,耐熔融氧化物(硅酸盐)侵蚀,电化学稳定并支持高电流密度。铱具有高熔点,良好的抗氧化性,优异的高温强度和延展性,是高温电化学工艺中阳极最有希望的候选材料。评估了通过从熔融盐电解质中电沉积铱来制造此类阳极的几种创新概念(EL-FormTM工艺)。研究了铱电沉积形成复杂形状成分和涂层的方法。制备了铱涂层石墨,多孔铱结构和固态铱阳极。电铸铱阳极的测试显示没有可见的降解。将介绍高表面惰性铱阳极的开发,制造和测试结果。

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