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Synthesis and Photocatalytic Property of BiVO4/FeVO4 Composite Novel Photocatalyst

机译:BiVO4 / FeVO4复合新型光催化剂的合成及光催化性能

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BiVO4/FeVO4 composite photocatalyst samples were prepared by calcining the mixture of FeVO4 and BiVO4 precusor which were prepared through liquid phase precipitation method for further increasing the photocatalytic efficiency of FeVO4. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microsoope(SEM) and specific surface area (BET). The photocatalytic activity was evaluated by photocatalytic degradation of methyl orange (MO) solution under visible light. The XRD patterns indicate that BiVO4/FeVO4 composite photocatalysts consist of triclinic phase and the lattice was not distorted beacause of doping Bi. But the morphology change greatly and the specific surface area has little change. In the experimental conditions used, the optimal photocatalytic activity for all the prepared samples was reached when BiVO4 doping was 22 at%. The degradation rate of MO was increased by 20%or so than that of pure FeVO4.
机译:通过煅烧通过液相沉淀法制备的FeVO4和BiVO4前驱物的混合物,进一步提高了FeVO4的光催化效率,制备了BiVO4 / FeVO4复合光催化剂样品。通过X射线衍射(XRD),扫描电子微量(SEM)和比表面积(BET)对催化剂进行了表征。通过在可见光下光催化降解甲基橙(MO)溶液来评估光催化活性。 XRD图谱表明BiVO4 / FeVO4复合光催化剂由三斜晶相组成,晶格未因掺杂Bi而畸变。但是形态变化很大,比表面积变化很小。在所用的实验条件下,当BiVO4掺杂为22 at%时,所有制备的样品均达到了最佳的光催化活性。 MO的降解率比纯FeVO4提高了20%左右。

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