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Microscale Modelling of Formation of Methane Hydrate in Porous Media

机译:多孔介质中甲烷水合物形成的微观模型

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Methane hydrate is a promising energy resource in the near future. One of the processes of its development in the sub-seabed sediments is depressurisation: pumping-up water through a well depressurises down to the extent lower than the equilibrium, and hydrate dissociates. However, hydrate dissociation is endothermic and temperature may become lower than the equilibrium point near a well and, hence, hydrate reforms. This may cause blockage of gas-water flow in the sediment. In this study, heat and mass transfer in water-gas-sand three-phases was analysed numerically by modelling them using a three-dimensional lattice Boltzmann method. Sand grains were assumed to be spherical for simplicity and the dissolution of methane into water through the interface was also analysed. At the same time, volumetric rate of hydrate formation was obtained by comparing the model results with those of measurement.
机译:甲烷水合物在不久的将来是一种有前途的能源。减压作用是在海底沉积物中发展的过程之一:通过井中的抽水使减压降到低于平衡的程度,并且水合物解离。但是,水合物的解离是吸热的,并且温度可能会低于井附近的平衡点,因此会发生水合物重整。这可能会阻止沉积物中的气水流动。在这项研究中,通过使用三维晶格玻尔兹曼方法对其进行建模,对水-气-沙三相中的传热和传质进行了数值分析。为了简单起见,假定沙粒为球形,并且还分析了甲烷通过界面溶解到水中的情况。同时,通过将模型结果与测量结果进行比较,获得了水合物形成的体积速率。

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