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Optimization of Reclaim Nitrogen and Phosphorus from Source-Separated Urine with Orthogonal Array Design

机译:正交阵列设计优化分离源尿中的氮和磷回收率

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Urine source separation technology is a new concept for municipal wastewater management. With chemical precipitation theory to reclaim nitrogen and phosphorus from source-separated urine, MgCl2•6H2O and Na2HPO4•12H2O were used as additives in the experiment to generate the magnesium ammonium phosphate (MAP) precipitation. The factors that affect MAP precipitation are choosed as following: pH, PO43-:NH4+, Mg2+:NH4+ and reaction temperature. Under the experimental conditions of reaction temperature=15°C, mixing speed=100r/min and reaction time=10min, the effects of pH, phosphate amount and magnesium ion concentration on nitrogen and phosphorous removal were investigated respectively. The optimum reaction conditions were got by orthogonal array experiment such as pH=9.5, Mg2+∶PO43-∶NH4+ =1.3:1.0:1.0, and the experimental results demonstrated that NH4+-N was effectively removed from initial 2850 mg/L down to about 125mg/L, residual phosphate was about 7mg/L. SEM and EDS figures indicate that the main precipitate are orthorhombic magnesium ammonium phosphate.
机译:尿液源分离技术是市政废水管理的新概念。根据化学沉淀理论从分离出的尿液中回收氮和磷,在实验中使用MgCl2•6H2O和Na2HPO4•12H2O作为添加剂,以生成磷酸镁铵(MAP)沉淀。选择影响MAP沉淀的因素如下:pH,PO43-:NH4 +,Mg2 +:NH4 +和反应温度。在反应温度为15℃,混合速度为100r / min,反应时间为10min的实验条件下,分别考察了pH值,磷酸盐含量和镁离子浓度对脱氮和脱磷的影响。通过正交实验确定了最佳反应条件,如pH = 9.5,Mg2 + ∶PO43-∶NH4 + = 1.3:1.0:1.0,实验结果表明,NH4 + -N可有效地从最初的2850 mg / L去除至约200mg / L。 125mg / L,残留磷酸盐约为7mg / L。 SEM和EDS数据表明,主要沉淀物是正交晶镁磷酸铵。

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