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Degradation of Polyacrylamide by Using a Novel Heterogeneous Catalyst in Fenton-Like System

机译:在Fenton-Like体系中使用新型多相催化剂降解聚丙烯酰胺

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Degradation of polyacrylamide(PAM) in aqueous solution was studied by using Fe2O3/Al2O3 or Fe2O3/carbon as heterogeneous catalyst in the presence of H2O2. In order to improve the catalytic activity, Effects of catalyst preparation conditions as impregnated materials, acid dipping and adding trace elements to catalyst activity were studied in the experiment. It was observed that Compared with Fe2(SO4)3, the Fe(Ⅲ) catalyst prepared with Fe(NO3)3 as the impregnated material showed better catalyst activity. The Fe2O3/Al2O3 and Fe2O3/carbon catalysts prepared with Acid immersion showed different catalyst activity, the former greatly increase the Catalytic degradation of PAM, In the present of 2.0g/L modified Fe2O3/Al2O3 catalyst and 0.6g/L H2O2, the best degradation ratio of M rates up to 97.9%. In addition, it was also found that The Fe2O3/Al2O3 and Fe2O3/carbon catalysts containing trace elements Cu both showed higher catalyst activity.
机译:以Fe2O3 / Al2O3或Fe2O3 /碳为非均相催化剂,在H2O2存在下,研究了聚丙烯酰胺(PAM)在水溶液中的降解。为了提高催化活性,研究了催化剂制备条件对浸渍材料,酸浸和添加微量元素对催化剂活性的影响。观察到,与Fe2(SO4)3相比,以Fe(NO3)3为浸渍材料制备的Fe(Ⅲ)催化剂具有更好的催化活性。酸浸法制备的Fe2O3 / Al2O3和Fe2O3 /碳催化剂表现出不同的催化剂活性,前者大大增加了PAM的催化降解。在2.0g / L的改性Fe2O3 / Al2O3催化剂和0.6g / L的H2O2的存在下,最佳M的降解率高达97.9%。另外,还发现含有微量元素Cu的Fe 2 O 3 / Al 2 O 3和Fe 2 O 3 /碳催化剂均显示出较高的催化剂活性。

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