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EFFECT OF SINTERING TEMPERATURE ON MECHANICAL PROPERTIES OF ELECTROSPUN SILICA NANOFIBERS

机译:烧结温度对电纺二氧化硅纳米纤维力学性能的影响

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Mechanical Properties of materials depend upon the crystal structure, presence of dislocations and slip planes in the unit cells. Nano-structures due to its nano scale size are expected to have defect free unit cells and hence posses very good mechanical properties. Electrospinning provides simple and cost effective means to produce nanofibers on a mass scale. These electrospun nanofibers could be subsequently used in woven composites to improve interlaminar properties. This paper addresses manufacturing of silica nanofibers by electrospinning and effect of sintering temperature on properties of these fibers. Electrospinning produces nanofibers by stretching liquid droplet emanating from spinnerate under the combined action of Columbic forces due to applied voltage and repulsion of charged ions. When the formed electrospun silica nanofibers are sintered at different temperatures, there is variation SiO_2 content due to evaporation of solvents. This results into variation in the mechanical properties of electrospun silica nanofibers based on the sintering temperature. Differential Scanning Calorimetric (DSC) studies are carried out to relate variation in SiO_2 content with sintering temperature. The mechanical properties of these electrospun fibers under various sintering temperatures are ascertained by evaluating their performance of composite laminates with electrospun interlaminate layers.
机译:材料的机械性能取决于晶格,晶胞中位错和滑移面的存在。由于其纳米级尺寸,纳米结构预期具有无缺陷的晶胞,因此具有非常好的机械性能。电纺丝提供了简单且具有成本效益的方式来大规模生产纳米纤维。这些电纺纳米纤维可随后用于机织复合材料中,以改善层间性能。本文探讨了通过静电纺丝制造二氧化硅纳米纤维以及烧结温度对其性能的影响。通过施加电压和带电离子的排斥,在哥伦布力的共同作用下,静电纺丝通过拉伸从纺丝状喷出的液滴来产生纳米纤维。当在不同温度下烧结形成的电纺二氧化硅纳米纤维时,由于溶剂的蒸发,SiO_2含量会发生变化。这导致基于烧结温度的电纺二氧化硅纳米纤维的机械性能变化。进行差示扫描量热法(DSC)研究,以将SiO_2含量的变化与烧结温度联系起来。这些电纺纤维在各种烧结温度下的机械性能可通过评估具有电纺夹层的复合层压板的性能来确定。

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