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DELIGNIFICATION OF BAGASSE BY SODA-OXYGEN PROCESS

机译:苏打-氧气法脱除甘蔗渣

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An experimental investigation on soda pulping of industrial bagasse was carried out in the laboratory with or without the presence of oxygen. The effects of temperature, percentage of alkali, and inhibitor like magnesium sulphate on yield, rejects, and kappa number were examined. One sample was also tested for EDTA in place of Mg~(++). The results were statistically evaluated. A new factor, h, proportional to H factor is proposed. The statistical models are built for yield, rejects and kappa number in terms of temperature, concentration, and proposed new h factor.From detailed analysis, it is found that yield of soda- oxygen pulp can be greatly enhanced by using inhibitors like MgSO4. Even E.D.T.A. can act as an inhibitor. Yield can be increased by about 15 - 20% in Soda - Oxygen process (Mg++ inhibitor) compared to soda pulp of bagasse. Maximum yield is obtained at 150°C and 14% alkali charge for cooking time of lhour and oxygen pressure of 5 bar. Center cook (150°C, 14%) was beaten to 45 °SR and sheets made yielded tensile of 3.39 kN/m and burst to be 196.13 kpa.m~2/g.An analytical model defining h proportional to H factor has been developed. Pulping experiments were carried out based on Statistical design of experimentation. The results indicate the following:(1) Soda - oxygen pulp yield can be greatly enhanced by using inhibitors like MgSO4.(2) Even E.D.T.A. can act as an inhibitor.(3) Yield can be increased by about 15 - 20% Soda - Oxygen (Mg++ inhibitor) compared to soda pulp of bagasse.(4) Maximum yield is obtained at 150°C and 14% alkali charge for cooking time of lhour and oxygen pressure of 5 bar.(5) Center cook (150°C, 14%) was beaten to 25°SR and sheets made gave tensile of 3.39 kN/m. Burst was found to be 196.13 kpa.m~2/g.Based on the data statistical multivariable nonlinear regression equations are developed for yield, rejects, and kappa Number. Two groups of models are attempted. Both the groups of statistical models are compared.The models predicted data agrees very closely with the experimental data with R~2 = 1. Therefore the models are found to be excellent. It is very difficult to distinguish between the two groups of models. Any one of them can be employed for prediction.
机译:在有氧或无氧条件下,在实验室中对工业蔗渣的苏打浆进行了实验研究。研究了温度,碱的百分比以及抑制剂(如硫酸镁)对产量,废品率和κ值的影响。还测试了一个样品的EDTA代替Mg〜(++)。对结果进行统计学评估。提出了一个与H因子成比例的新因子h。建立关于温度,浓度和建议的新h因子的产量,次品率和kappa值的统计模型。 从详细的分析中可以发现,通过使用MgSO4等抑制剂可以大大提高苏打纸浆的产量。即使是E.D.T.A.可以充当抑制剂。与甘蔗渣的苏打浆相比,苏打-氧气法(Mg ++抑制剂)的收率可提高约15-20%。在1小时的烹饪时间和5 bar的氧气压力下,在150°C和14%的碱度下可获得最大产量。将中心蒸煮器(150℃,14%)搅拌至45℃SR,制成的片材的拉伸强度为3.39kN / m,破裂为196.13kpa.m〜2 / g。 已经开发了定义与h因子成比例的h的分析模型。根据实验的统计设计进行制浆实验。结果表明: (1)通过使用诸如MgSO4的抑制剂,可以大大提高苏打-纸浆的产量。 (2)即使是E.D.T.A.可以充当抑制剂。 (3)与蔗渣的苏打浆相比,苏打-氧气(Mg ++抑制剂)的产量可提高约15-20%。 (4)在1小时的烹饪时间和5 bar的氧气压力下,在150°C和14%的碱度下获得最大产量。 (5)将中心蒸煮器(150℃,14%)搅拌至25℃SR,制成的片的拉伸力为3.39kN / m。发现爆发为196.13kpa.m〜2 / g。 根据数据,针对产量,次品率和卡伯值开发了统计多元非线性回归方程。尝试了两组模型。比较两组统计模型。 该模型的预测数据与R〜2 = 1的实验数据非常吻合。因此,发现该模型非常出色。很难区分两组模型。它们中的任何一个都可以用于预测。

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