Nano Effects of Helium-plasma Treatment Nano-SiO_2 Sol-gel Coating UHMWPE Filaments

摘要

The effects of helium-plasma treatment on tensile deformation of nano-SiO_2 sol-gel coating UHMWPE filaments (HONSUHMWPE) were studied and a new concept for the nano-structural interphase between fiber surface and nano-coating was provided. The tensile test results showed that in addition to the enhanced ductility of UHMWPE filaments by nano-SiO_2 sol-gel coating UHMWPE filaments treated by helium-plasma, the activation volumes of UHMWPE filaments untreated and treated with helium-plasma ranging from 1101.875 to 16603.07(nm)~3 by following Eyring's equation were important descriptors for the properties of the nano-structural interphase between fiber surface and nano-coating, From the results of SEM and FTIR, it was observed that the remarkable uniform dispersion of the nano-SiO_2 coating of the UHMWPE filaments modified with helium plasma not only introduced the activated functional groups, but also formed a protective layer on the fiber surfaces.