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Ultrasonic Wave Velocities Associated with Formation and Dissociation of Methane Hydrate in Artificial Sandy Sediment

机译:超声波与人工沙质沉积物中甲烷水合物形成和解离的关系

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To determine whether ultrasonic wave velocities are affected by the occurrence and amount of methane hydrate in the pore spaces of sediments, we measured ultrasonic velocities in artificial methane hydrate-bearing sandy sediments during the formation and dissociation processes of methane hydrate. An artificial core specimen was made based on the properties of a natural core recovered from a site in the Nankai Trough near Japan. A core holder was used that permitted the independent application of both confining and pore pressures to the artificial core using a rubber sleeve and two syringe pumps. Piezoelectric ceramic sensors were positioned at both end faces of the core and used to oscillate and detect the compressional and shear ultrasonic waves. The formation of methane hydrate, by pressurizing water in the pore spaces of the core sample using methane gas, was associated with an increase in both wave velocities. The increase in ultrasonic velocities was particularly marked at saturations of methane hydrate in the pore spaces above 30% and the maximum velocity of the compressional wave exceeded 3,000 m/s. While ultrasonic wave velocities decreased with the dissociation of methane hydrate due to depressurization or heating, they exhibit hysteresis during formation and dissociation. These findings indicate that the velocities depend on the occurrence of methane hydrate in pore spaces as well as the concentration.
机译:为了确定超声波速度是否受沉积物孔隙中甲烷水合物的出现和数量的影响,我们在甲烷水合物的形成和分解过程中,测量了含人造甲烷水合物的砂质沉积物中的超声波速度。根据从日本附近的南海海槽中某个地点回收的天然岩心的特性制作了人造岩心标本。使用了一个芯架,该芯架允许使用橡胶套和两个注射泵将围压和孔隙压力独立地施加到人造芯上。压电陶瓷传感器位于磁芯的两个端面,用于振荡和检测压缩超声波和剪切超声波。通过使用甲烷气体对岩心样品孔隙中的水进行加压而形成甲烷水合物,这与两种波速的增加有关。超声波速度的增加尤其明显地表现在孔隙空间中甲烷水合物的饱和度超过30%,并且压缩波的最大速度超过3,000 m / s。尽管由于减压或加热而使超声波速度随甲烷水合物的解离而降低,但它们在形成和解离期间显示出滞后现象。这些发现表明,速度取决于孔隙空间中甲烷水合物的发生以及浓度。

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