首页> 外文会议>Annual meeting of the Adhesion Society;Meeting of the Adhesion Society;World congress on adhesion and related phenomena;WCARP-II >Molecular Weight Dependence of Liquefied Products on Curing Reaction in Resorcinol Liquefied Wood Adhesives
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Molecular Weight Dependence of Liquefied Products on Curing Reaction in Resorcinol Liquefied Wood Adhesives

机译:间苯二酚液化木材胶粘剂中液化产物分子量对固化反应的依赖性

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Resorcinol liquefied product obtained by exhuastive solvolysis were examined in terms of reactivity whether they would be comparable adhesive resins to resorcinol-phenol co-condensate adhesives. The results were as follws, 1) RLP presented rather higher activation energy and Tmax than its fractions and a commercial resorcinolic resin. The addition of Na_2CO_3 to RLP, however, lowered the activation energy and Tmax. 2) The pH change toward alkaline side in cure system with addition of Na_2CO_3 was considered to contribute to lowering activation energy of resorcinol and RLP-L, while Na_2CO_3 itself worked on lowering activation energy of RLP and RLP-H as an acceleralater. We concluded that RLP would be a promising platform of adhesive resin comparable to resorcinol-phenol co-condensate resins if some modification could be applied, i.e. addition of Na_2CO_3 in cure system.
机译:检查了通过溶剂分解法得到的间苯二酚液化产物的反应性,看它们是否与间苯二酚-苯酚共缩合物粘合剂相当。结果如下:1)RLP具有比其馏分和市售间苯二酚树脂更高的活化能和Tmax。但是,将Na_2CO_3添加到RLP中会降低活化能和Tmax。 2)认为在固化体系中添加Na_2CO_3会使pH值向碱性侧变化,这有助于降低间苯二酚和RLP-L的活化能,而Na_2CO_3本身则在降低RLP和RLP-H的活化能方面起到了促进作用。我们得出的结论是,如果可以进行某些改性,即在固化体系中添加Na_2CO_3,RLP将是与间苯二酚-苯酚共缩合物树脂相当的粘合剂树脂的有前途的平台。

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