首页> 外文会议>National meeting of the American Chemical Society >Polymer Glasses: Thermodynamic and Relaxational Aspects
【24h】

Polymer Glasses: Thermodynamic and Relaxational Aspects

机译:聚合物玻璃:热力学和松弛方面

获取原文

摘要

Starting in the melt, proceeding to the transition region and continuing into the glassy state, sets of equilibrium, and non-equilibrium processes are considere.d We examine the consequences of a unified view dervied from a lattice-hole model, involving a hole fraction h to account for the structural disorder. The role of h as a free volume quantity is explored in various processes. A comparison of h with a free volume quantity directly measured by positron spetroscopy shows a gratifying ocncordance in the melt. Possible resolutions of differneces in the glass are examined. Correlations between equation of state and other physical properties in melt and glass with h as the connecting bridge are extended to time dependent processes.
机译:从熔体开始,继续过渡到玻璃态,考虑了平衡集和非平衡过程。d我们研究了由晶格-孔模型衍生的统一视图的结果,其中涉及孔分数h解释结构异常。 h在各种过程中都作为自由体积量发挥着作用。将h与通过正电子显微镜直接测量的自由体积进行比较,可得出熔体中的可喜现象。检查玻璃中微分的可能分辨率。以h为连接桥的熔体和玻璃中的状态方程与其他物理性质之间的相关性扩展到了随时间变化的过程。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号