Some unusual aspects of unimolecular falloff of importance in combustion modeling

摘要

This review is concerned with the appearance and treatment of unimolecular falloff under typical combustion conditions where it represents one of the most difficult problems in modeling.It begins with the proposal of a normal or standard form of RRKM theory,most appropriate for hydrocarbons in rare gases,whilch can be sued for evalaution and prediction of falloff effects.Sucessful applicaitosn of this standard model to large-molecule dissociation are presented.Several important and ocmmon deviations from the standard model are then discussed.