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Pyrolysis of cyclopentadiene: rates for initial C-H bond fission and the decomposition of c-C_5H_5

机译：环戊二烯的热解：初始C-H键裂变和c-C_5H_5分解的速率

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The pyrolysis of yclopentadiene has bene observed in shock waves with two complementary mehtods: time-of-flight mass spectrolmetry (TOFMS) and laser-schlieren (LS) densitometry.Experiments encompassed the ranges 100-450 Torr 15000-2500 K.The low-temperature LS experiments sho brief early maxima indicative of chain raeadction initiated by C-H fisison.

机译：环戊二烯的热解可以在冲击波中观察到，它具有两种互补的方法：飞行时间质谱（TOFMS）和激光雪利仑（LS）密度法，实验范围为100-450 Torr 15000-2500 K.低温LS实验应显示短暂的早期最大值，表明CH裂变引发的链断裂。

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《International symposium on combustion》|1998年|p.143-150|共8页
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R.D.Kern; Q.Zhang; J.Yao; B.S.Jusic; R.S.Tranter; M.A.Greybill; J.H.Kieffer;
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中图分类化学;
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1. Electrophilic, ambiphilic, and nucleophilic C-H bond activation: Understanding the electronic continuum of C-H bond activation through transition-state and reaction pathway interaction energy decompositions [J] . Ess D.H., Goddard W.A., Periana R.A. Organometallics . 2010,第23期

机译：亲电，歧义和亲核C-H键活化：通过过渡态和反应途径相互作用的能量分解，了解C-H键活化的电子连续性
2. Competitive C-H and O-D bond fission channels in the UV photodissociation of the deuterated hydroxymethyl radical CH2OD [J] . Feng L., Demyanenko AV., Reisler H. The Journal of Chemical Physics . 2004,第14期

机译：氘代羟甲基自由基CH2OD的紫外光解离中竞争的C-H和O-D键裂变通道
3. Matrix Isolation Infrared and ab Initio Study of the 1:1 Complexesof Cyclopentadiene with Nitrogen and Oxygen Bases: C-H···N(O) Hydrogen Bonding Involving an sp~3-Hybridized Carbon [J] . Mark A.Hilfiker, Erin R.Mysak, Cindy Samet, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第13期

机译：环戊二烯与氮和氧碱的1：1配合物的基质分离红外和从头算研究：C〜H···N（O）氢键涉及sp〜3-杂化碳
4. Pyrolysis of cyclopentadiene: rates for initial C-H bond fission and the decomposition of c-C_5H_5 [C] . R.D.Kern, Q.Zhang, J.Yao, International symposium on combustion . 1998

机译：环戊二烯的热解：初始C-H粘结裂变的速率和C-C_5H_5的分解
5. Molecular beam mass spectrometry measurement of 1-butene pyrolysis and combustion products: Stable and active species profiles, and, Combustion modeling of benzene, phenol, anisole and cyclopentadiene thermodynamic parameters and elementary reaction kinetic mechanism. [D] . Zhong, Xian. 1998

机译：1-丁烯热解和燃烧产物的分子束质谱测量：稳定的活性物种分布图，以及苯，苯酚，苯甲醚和环戊二烯的热力学参数和基本反应动力学机理的燃烧模型。
6. C-H Bond Functionalization via Hydride Transfer: Formation of α-Arylated Piperidines and 1234-Tetrahydroisoquinolines via Stereoselective Intramolecular Amination of Benzylic C-H Bonds [O] . Paul A. Vadola, Ignacio Carrera, Dalibor Sames -1

机译：通过氢化物转移C-H键官能：通过苄型C-H键的立体选择性分子内胺化α芳基化哌啶和1234-四氢异喹啉的形成
7. Medium effects on a C-H bond fission reaction. Solvent and salt effects on the solvolysis of arylsulfonylmethyl perchlorates. [O] . Menninga Lubbertus 1976

机译：对C-H键裂变反应有中等影响。溶剂和盐对芳基磺酰甲基高氯酸盐溶剂分解的影响。
8. Direct Selective Acylation of an Unactivated C-H Bond in a Caged Hydrocarbon.Approach to Systems for C-H Bond Functionalization That Proceed Catalytically and Selectively at High Substrate Conversion [R] . Prosser-McCartha, C. M., Hill, C. L. 1990

机译：笼型烃中未活化C-H键的直接选择性酰化。用于C-H键官能化的系统，在高基质转化下催化和选择性地进行

Pyrolysis of cyclopentadiene: rates for initial C-H bond fission and the decomposition of c-C_5H_5

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