Quantum corrections to a semiclassical approximation for describingvibration-rotation spectra of nonrigid molecules: the example of an asymmetrictop,

摘要

Abstract: Quantum corrections to a semiclassical approximation for an asymmetric top are derived on the basis of the semiclassical self-consistent vibration-rotation fields theory. This can be considered as a foundation for describing of highly excited vibration-rotation states of nonrigid molecules. !10