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Reactive pulsed laser deposition: a tool for obtaining high-quality piezoelectric thin films

机译:反应性脉冲激光沉积:获得高质量压电薄膜的工具

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Abstract: High quality ZnO, AlN, PZT thin films were deposited on different substrates (Si, sapphire, Corning glass) by reactive pulsed laser deposition technique using a Nd-YAG laser (lambda equals 1.06 micrometer, t$-FWHM$/ equals 10 ns, 0.3 J/pulse) as laser source. The depositions were performed in a stainless steel vacuum chamber (base pressure less than 10$+$MIN@6$/ mbar) as follows: (1) Zn and PZT targets in high purity oxygen atmosphere, (2) Al target in ultrahigh purity nitrogen reactive atmosphere. Low collector temperatures (in the range of 0 - 350 degrees Celsius), high distance target collector (4 - 7 cm), high laser intensities, reactive gas pressure in the range of 10$+$MIN@3$/ - 10$+$MIN@1$/ mbar were found to be mandatory requirements for obtaining uniform, appropriate crystalline orientation thin films, with thickness in the range of 2 - 4 micrometer. Typical analysis as: x-ray diffraction, cross section SEM, x-ray photoelectron spectroscopy (XPS), Fourier transmission infrared spectroscopy (FTIR), secondary ion mass spectroscopy (SIMS), optical absorption spectroscopy were used to characterize the deposited films. They evidence the stoichiometric composition, crystalline structure with the c-axis perpendicular to substrate surface, columnar structure, etc. For the piezoelectric properties studies special structures were prepared: substrate (Si, etc.)/Cr(100 angstrom)/Au(1000 angstrom)/ZnO(or AlN, or PZT)/Al in order to configure an electroacoustic transducer for bulk acoustic wave generation and detection. The measurements confirm the good properties of the deposited films. !12
机译:摘要:使用Nd-YAG激光(λ等于1.06微米,t $ -FWHM $ /等于10)通过反应脉冲激光沉积技术在不同的衬底(硅,蓝宝石,康宁玻璃)上沉积高质量的ZnO,AlN,PZT薄膜。 ns,0.3 J / pulse)作为激光源。沉积是在不锈钢真空室(基本压力低于10 $ + MIN @ 6 $ / mbar)中进行的,操作如下:(1)高纯氧气氛中的Zn和PZT靶,(2)超高纯铝靶。氮气反应气氛。较低的收集器温度(在0至350摄氏度范围内),远距离目标收集器(4至7厘米),高激光强度,反应性气体压力在10 $ + $ MIN @ 3 $ /--10 $ +范围内发现$ MIN @ 1 $ / mbar是获得厚度在2-4微米范围内的均匀,合适的晶体取向薄膜的强制性要求。典型分析为:X射线衍射,横截面SEM,X射线光电子能谱(XPS),傅立叶透射红外光谱(FTIR),二次离子质谱(SIMS),光学吸收光谱来表征沉积膜。他们证明了化学计量的组成,c轴垂直于基材表面的晶体结构,柱状结构等。为进行压电性能研究,制备了特殊结构:基材(Si等)/ Cr(100埃)/ Au(1000)埃/ ZnO(或AlN或PZT)/ Al,以配置用于体声波生成和检测的电声换能器。测量结果证实了沉积膜的良好性能。 !12

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