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Heat effects occurring during the reactions between gaseous chlorine and strong aqueous bases

机译:气态氯与强碱之间发生热效应

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Abstract: Experiments were conducted in order to determine the heat effects which accompany the reactions between gaseous chlorine and strong, concentrated aqueous base solutions. The bases used were potassium hydroxide (KOH) and potassium hydroperoxide (KO$-2$/H). Solution concentrations ranged up to 7 M. Chlorine gas (Cl$-2$/) was bubbled into the base solution which was thermally isolated from the surroundings in a Dewar vessel. From the experimental data, enthalpies of reaction and enthalpies of formation for the concentrated basic solutions were calculated.!5
机译:摘要:为确定伴随气态氯气与浓,浓碱水溶液之间反应的热效应,进行了实验。所用的碱是氢氧化钾(KOH)和氢过氧化钾(KO $ -2 $ / H)。溶液浓度高达7M。将氯气(Cl $ -2 $ /)鼓入到基本溶液中,该溶液与杜瓦瓶中的周围环境热隔离。根据实验数据,计算出浓碱性溶液的反应焓和形成焓。!5

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