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Fretting-corrosion processes of metal-ceramic joints in the artificial saliva environment

机译:人工唾液环境下金属陶瓷接头的微动腐蚀过程

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Corrosion and fretting-corrosion processes are one of the most significant problems, involving medical construction elements. Friction under conditions of micro-movements often initiates the corrosion processes, which are intensified in the presence of human body fluids [1]. Wear effect is growing intensively especially in the joint elements (micro-contact areas). This results in formation of biomaterials wear products, which are harmful to human body. It is an undeniable fact, which has been confirmed by a number of clinical trials [2]. The released metal ions may cause local or systemic response of the organism, and may cause many diseases (inflammation, allergic reaction, metalosis). This can lead to failure of medical therapy. Fretting processes have attracted great attention, but we still lack information about dental organs. Metal-metal joints are mostly used in medical applications, but they are not always beneficial, due to increased risk of galvanic corrosion, which is why metal-plastic or metal-ceramics are becoming more popular. In this work, in vitro studies of fretting and fretting-corrosion processes of selected biomaterials in metal-alumina ceramics systems used in prosthetic and dental surgery were conducted. The studies were realized with the use of originally constructed pin-on-disc type fretting tester, combined with electrochemical measurement system. This apparatus allowed to conduct potentiodynamic corrosion tests in fretting conditions. Simultaneous registration of both processes allows for better analysis of actual phenomenon taking place in the living organism. Observations of samples' morphology by means ofscanning electron microscope (SEM) and confocal laser microscope (CLM) enable to determine the volume of material losses and thus to evaluate fretting and fretting-corrosion wear. Obtained results indicate that friction have significant impact on the durability of investigated biomaterials. Conducted tests are exploratory in nature and oriented, in particular, towards gaining better understanding of the destruction mechanisms of biomaterials and thus, extending the time of their reliable operation in medical applications.
机译:腐蚀和微动腐蚀过程是最重要的问题之一,涉及医疗构造要素。微动条件下的摩擦通常会引发腐蚀过程,而腐蚀过程会在存在人体液体的情况下加剧[1]。磨损效果特别是在接头元件(微接触区域)中迅速增强。这导致形成对人体有害的生物材料磨损产品。这是不可否认的事实,已被许多临床试验证实[2]。释放的金属离子可能引起生物体的局部或全身反应,并可能引起许多疾病(炎症,过敏反应,金属症)。这可能导致药物治疗失败。微动过程引起了极大的关注,但我们仍然缺乏有关牙齿器官的信息。金属-金属接头最常用于医疗应用,但由于电偶腐蚀的风险增加,因此它们并不总是有益的,这就是为什么金属塑料或金属陶瓷越来越受欢迎的原因。在这项工作中,进行了在修复和牙科手术中使用的金属-氧化铝陶瓷系统中所选生物材料的微动和微动腐蚀过程的体外研究。这项研究是通过使用最初构造的销钉盘式微动测试仪并结合电化学测量系统来实现的。该设备允许在微动条件下进行电位动力学腐蚀测试。同时注册两个过程可以更好地分析活生物体中发生的实际现象。通过扫描电子显微镜(SEM)和共聚焦激光显微镜(CLM)观察样品的形态,可以确定材料损失的量,从而评估微动磨损和微动腐蚀磨损。所得结果表明,摩擦对所研究的生物材料的耐久性有重大影响。进行的测试本质上是探索性的,尤其是旨在更好地了解生物材料的破坏机理,从而延长了其在医学应用中可靠运行的时间。

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