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Corrosion of cans in collections: the results of the CANS project

机译:罐中的罐头腐蚀:CANS项目的结果

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The CANS project, started in 2014 and funded by the Swiss National Science Foundation, is an interdisciplinary research that aims at proposing conservation solutions for food cans still retaining their original content in museums' collections. During the project, the following activities were carried out and are presented in this paper: Evaluation of the state of conservation of full cans in Swiss collections. Around 150 cans from 5 different collections were examined and documented. Correlations between degradation conditions, content and age of the can were settled. Extensive characterization of the metal structure of the container, concerning the stratigraphy and the porosity. Different analytical and electrochemical techniques were used for this purpose: SEM-EDX. Auger Spectroscopy, X-Ray Fluorescence spectroscopy, Electrochemical Impedance Spectroscopy and Iron Exposure Value. Corrosivity variations of the food in different ageing conditions. Dozens of cans were stored for more than one year at three different temperatures: room temperature (~20°C), 4°C and 40°C. The variations in term of corrosivity of the food and its effect on the metallic container were assessed electrochemically and spectroscopically. Monitoring of the gas production inside the can. Due to the interaction between the metallic container and the acid food, corrosion phenomena can occur inside the can, with the consequent production of hydrogen that can lead to the swelling of the container. The importance of the monitoring and control of the swelling is crucial, in particular in museums' facilities, to avoid the bursting and the damaging of the objects exposed or stored nearby. Preventive conservation recommendations for full cans in collections and intervention methodologies will also be illustrated in this paper.
机译:CANS项目于2014年启动,由瑞士国家科学基金会资助,是一项跨学科研究,旨在为仍在博物馆藏品中保留其原始内容的食品罐提出保护方案。在该项目期间,进行了以下活动,并在本文中进行介绍:对瑞士藏品中完整罐头的保存状态进行评估。检查并记录了来自5个不同馆藏的大约150个罐头。确定了降解条件,罐的含量和使用年限之间的相关性。有关地层和孔隙率的容器金属结构的广泛表征。为此使用了不同的分析和电化学技术:SEM-EDX。俄歇光谱,X射线荧光光谱,电化学阻抗光谱和铁暴露值。食物在不同老化条件下的腐蚀性变化。数十个罐子在三种不同的温度下分别存放了一年以上:室温(〜20°C),4°C和40°C。用电化学和光谱法评估了食品腐蚀性及其对金属容器的影响。监视罐内的气体产量。由于金属容器和酸性食品之间的相互作用,罐内可能发生腐蚀现象,并随之产生氢气,这会导致容器膨胀。监测和控制膨胀的重要性至关重要,尤其是在博物馆的设施中,以避免爆炸或损坏附近暴露或储存的物体。本文还将说明完整罐的预防性养护建议和干预方法。

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