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Wet Adhesion of Graphene

机译:石墨烯的湿粘合

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MD simulations were conducted to study the traction-separation behaviors for wet adhesion between graphene and a-SiO_2. Three stages of the traction-separation relations are identified and they are analyzed by simple continuum models. The work of separation (per unit area) is found to be close to the theoretical value (60.0 mJ/m~2) dictated by the interaction potential between graphene and water. The maximum traction is found to be set by the critical stress for cavitation at the water/graphene interface (around 90 MPa in the present study). With morphological evolution of water from cavitation to capillary bridging, the range of interaction extends to about 3 nm before complete separation of graphene. Compared to van der Waals interactions for dry adhesion between graphene and a-SiO2, the work of separation for wet adhesion is considerably smaller, the maximum traction is lower, but the range of interaction is longer. It is noted that the properties of wet adhesion depend sensitively on the graphene-water interactions, which may vary considerably between hydro-phobic and hydrophilic interactions.
机译:进行了MD模拟,研究了石墨烯与a-SiO_2之间湿式附着力的牵引分离行为。确定了牵引分离关系的三个阶段,并通过简单的连续模型对其进行了分析。发现分离功(每单位面积)接近于由石墨烯与水之间的相互作用电势所决定的理论值(60.0 mJ / m〜2)。发现最大牵引力是由水/石墨烯界面处的气蚀临界应力(在本研究中约为90 MPa)确定的。随着水从空化到毛细管桥的形态演化,在石墨烯完全分离之前,相互作用的范围扩展到约3 nm。与用于石墨烯和a-SiO2之间干粘合的范德华相互作用相比,湿粘合的分离功小得多,最大牵引力较低,但相互作用范围较长。注意,湿粘合的性质敏感地取决于石墨烯-水的相互作用,这在疏水和亲水相互作用之间可能有很大的不同。

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