Kinetics and mechanism of thermal decomposition of 2,4-dinitro-2,4-diaza-6-R-6,6-dinitrohexane

摘要

Kinetics and mechanism of the thermal decomposition of gem-dinitroethyl-di-N-nitramines is investigated. The limiting stage is established and its activation parameters are determined. It is shown that logarithms of the rate constants and activation energies correlate with the steric constants of substituents E_s. The received correlation equations allow forecasting synthesis of unstudied compounds of this row with the set parameters for chemical stability.