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Influence of Small Defects Produced in Electrolytes during Manufacturing Processes on Operated SOFCs

机译:生产过程中电解液中产生的小缺陷对操作的SOFC的影响

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The influence of gas leakage through penetrated holes introduced during fabrication was experimentally evaluated using in-situ Raman scattering spectroscopy. Gas chromatography analysis of pressure differences between the anode and the cathode revealed that the gas leakage through the holes was dominated by gas diffusion through the anode, and that the pressure difference did not influence the amount of gas leakage. In-situ measurements in an operated cell with a hole revealed combustion between leaked H_2 and air occurred around the hole, the O_2 partial pressure at this hole was not sufficiently low to reduce NiO, and the temperature increased by almost 10°C around the hole. In contrast, no influence on stress distributions was observed.
机译:使用原位拉曼散射光谱通过实验评估了在制造过程中通过穿孔引入的气体泄漏的影响。气相色谱分析阳极和阴极之间的压力差表明,通过孔的气体泄漏主要是通过阳极的气体扩散,并且压力差不影响气体的泄漏量。在有孔的操作单元中进行的现场测量表明,泄漏的H_2和空气之间发生了燃烧,孔周围的O_2分压不够低,无法还原NiO,孔周围的温度几乎升高了10°C 。相反,未观察到对应力分布的影响。

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