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Accelerated Lifetime Tests for SOFCs

机译:SOFC的加速寿命测试

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摘要

Conventional lifetime analysis for solid oxide fuel cells requires considerable testing time and capacities. In case of application oriented testing durations of several years, the results cannot be used for the continued development of cells and stacks before the test is finished. Therefore accelerated lifetime tests, which enable a rapid degradation analysis, would be highly desirable. In this paper we will show that the overall degradation rate of a single cell can hardly be used in accelerated lifetime tests. It is required to evaluate the degradation of the electrochemical processes in each cell component. The degradation of cathode, electrolyte and anode was deconvoluted by (ⅰ) impedance spectroscopy, (ⅱ) distribution of relaxation times data analysis and (ⅲ) a subsequent CNLS-Fit. Such approach can provide stress level dependencies for the aging of individual electrochemical processes in the cell.
机译:固体氧化物燃料电池的常规寿命分析需要大量的测试时间和容量。如果面向应用程序的测试持续了数年,那么在完成测试之前,结果不能用于电池和电池组的持续开发。因此,非常需要能够进行快速降解分析的加速寿命测试。在本文中,我们将表明,单个电池的整体降解率几乎不能用于加速寿命测试中。需要评估每个电池组件中电化学过程的退化。阴极,电解质和阳极的降解通过(ⅰ)阻抗谱,(ⅱ)弛豫时间数据分析的分布和(ⅲ)随后的CNLS-Fit解卷积。这种方法可以为电池中各个电化学过程的老化提供应力水平依赖性。

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