There were prepared lead electrode with electrochemical deposition. This electrode was used as cathode with LiCoCte as anode in electrochemical cell. This measure simulated lithium-ion cell for studying intercalation of lithium. Electrochemical intercalation of lead is important for the search of novel lithium batteries. It is known, that there elements of IVth group of periodic system of elements are among the candidates for that purpose. [1-4] hi the case of elemental tin or silicium a great difficulty arises from extremely great volume change in the process of intercalation. A hypothesis has arisen that this can be bypassed by the use of nanostructured or microstructured metal as the host substance for the intercalation, the voids in them would absorb the volume changes without disintegration of the electrode material. The electrodeposition of elements from solutions of metal halides or metaloorganic compounds dissolved in aprotic polar solvents was expected to be the way how to obtain such materials. This contribution describes some experimental results from a section of our research in mentioned subject.
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