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Measurement and Characterization of Mid-wave Infrared Radiation in CO_2 Shocks

机译:CO_2冲击波中波红外辐射的测量与表征

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We present the characterization of infrared radiation obtained in the NASA Ames Electric Arc Shock Tube at velocities from 3-7.5 km/s and freestream densities from 4.7-24 g/m~3 (corresponding to ground test pressures of 0.2 to 1.0 Torr), which are relevant to Mars entry conditions. The IR radiation is shown to decrease with increasing velocity over this range, and is expected to be largest at 3 km/s. Based on this data, an estimated relationship for (near) peak radiative heating is given as 20 W/cm~2 for Mars Science Laboratory, which compares well to the 18 W/cm~2 discrepancy (out of 35 W/cm~2) observed on its stagnation line sensor. Analysis of the experimental data shows that spectral profiles are predicted well by NEQAIR for most conditions. The only exception is the 2.7 μm band at high temperature, which is underpredicted. Spatially resolved data are used for comparison against proposed kinetic models for CO_2 shock environments. No one model matches the data at all conditions, but each may agree over some velocity range. A simplified three reaction model is shown to predict the post-shock decay well, while matching the radiative magnitude to within 30-70% in the velocity range 3.0-5.7 km/s. Attempts to extract reaction rates directly from the data shows the dissociation rate to be controlled by O atom exchange, and show good consistency with published kinetic rates for a velocity of 3 km/s. At higher velocity, the initial kinetics occur in thermal non-equilibrium, suggesting further study of these mechanisms are warranted.
机译:我们介绍了在NASA Ames电弧冲击管中以3-7.5 km / s的速度和4.7-24 g / m〜3的自由流密度(对应于0.2至1.0 Torr的地面测试压力)获得的红外辐射的特性,与火星进入条件有关。在此范围内,IR辐射随速度的增加而降低,并且预计在3 km / s时最大。根据此数据,火星科学实验室的(近)峰值辐射加热的估计关系为20 W / cm〜2,与18 W / cm〜2的差异(35 W / cm〜2中的差异)相当。 )在停滞线传感器上观察到。对实验数据的分析表明,NEQAIR在大多数情况下都能很好地预测光谱轮廓。唯一的例外是高温下的2.7μm波段,这是被低估的。空间分解的数据用于与CO_2冲击环境的拟议动力学模型进行比较。没有一个模型在所有条件下都能匹配数据,但是每个模型都可以在某个速度范围内达成一致。显示了一个简化的三个反应模型,可以很好地预测震后衰减,同时在3.0-5.7 km / s的速度范围内将辐射强度匹配在30-70%之内。尝试直接从数据中提取反应速率表明解离速率受O原子交换控制,并且对于3 km / s的速度显示与公布的动力学速率具有良好的一致性。在较高的速度下,初始动力学发生在热不平衡中,这表明有必要进一步研究这些机理。

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