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Magnetically Recyclable Nanocatalysts: Eco-friendly Solutions for Green Catalysis

机译:磁性可循环利用的纳米催化剂:绿色催化的环保解决方案

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In the last decades, there has been an escalating concern about environmental protection, which motivated the quest for novel cost-effective sustainable catalytic technologies. With the advent of Nanoscience, magnetic nanomaterials such as transition metal nanoferrites, conquered new horizons in Green Catalysis. By combining the intrinsic advantages of nanosize materials with the easy recovery by magnetic separation, magnetic nanoparticles unlocked the gateway to a new generation of recyclable nanocatalysts. This work provides an overview of our recent breakthroughs in the design of magnetically recyclable nanocatalysts. We will start by presenting their application as catalyst supports for the immobilization of (a) a metal complex with high catalytic efficiency in oxidation reactions and (b) gold nanoparticles catalytically active in the 4-nitrophenol reduction. In a distinct approach, superparamagnetic nanoferrites were used as intrinsic catalysts in the degradation of a dye.
机译:在过去的几十年中,人们对环境保护的关注日益升级,这促使人们寻求新颖的,具有成本效益的可持续催化技术。随着纳米科学的出现,诸如过渡金属纳米铁氧体之类的磁性纳米材料在绿色催化领域开辟了新的领域。通过将纳米级材料的固有优势与通过磁分离的容易回收相结合,磁性纳米粒子为通往新一代可回收纳米催化剂的途径打开了大门。这项工作概述了我们在可循环利用的磁性纳米催化剂设计方面的最新突破。我们将首先介绍它们作为固定化催化剂的载体的应用(a)在氧化反应中具有高催化效率的金属配合物和(b)在4-硝基苯酚还原中具有催化活性的金纳米颗粒。在一种独特的方法中,超顺磁性纳米铁氧体被用作染料降解中的内在催化剂。

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