Atomic Layer Deposition of Ruthenium on Platinum Anode for Direct Methanol Solid Oxide Fuel Cells

机译：直接甲醇固体氧化物燃料电池铂阳极上钌的原子层沉积

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Ru was deposited onto Pt by atomic layer deposition to fabricate anodes for direct methanol solid oxide fuel cells (SOFCs). The performance of the SOFCs with Ru/Pt anodes regarding methanol oxidation was compared with that of the SOFCs with pure Pt anodes. The values of maximum power density of the Ru/Pt SOFC were 4.1 mW/cm~2 at 400 °C and 7.8 mW/cm~2 at 450 °C. The electrochemical properties of the SOFCs were analyzed by the electrochemical impedance spectroscopy. The morphology of Ru on the microporous Pt was investigated via scanning electron microscopy.

机译：通过原子层沉积将Ru沉积到Pt上，以制造用于直接甲醇固体氧化物燃料电池（SOFC）的阳极。将具有Ru / Pt阳极的SOFC的甲醇氧化性能与具有纯Pt阳极的SOFC的性能进行了比较。 Ru / Pt SOFC的最大功率密度在400°C下为4.1 mW / cm〜2，在450°C下为7.8 mW / cm〜2。通过电化学阻抗谱分析了SOFC的电化学性质。通过扫描电子显微镜研究Ru在微孔Pt上的形态。

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《International Symposium on Solid Oxide Fuel Cells》|2013年|3059-3062|共4页
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H. J. Jeong; J. W. Kim; K. Bae; H. Jung; J. H. Shim;
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1. Platinum-Ruthenium Heterogeneous Catalytic Anodes Prepared by Atomic Layer Deposition for Use in Direct Methanol Solid Oxide Fuel Cells [J] . Jeong Heon Jae, Kim Jun Woo, Bae Kiho, ACS catalysis . 2015,第3期

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3. An organometallic deposition of ruthenium adatoms on platinum that self poisons at a specific surface composition. A direct methanol fuel cell using a platinum-ruthenium adatom anode catalyst [J] . Dianxue Cao, Steven H. Bergens Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2002,第1a2期

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4. Atomic Layer Deposition of Ruthenium on Platinum Anode for Direct Methanol Solid Oxide Fuel Cells [C] . H. J. Jeong, J. W. Kim, K. Bae, International Symposium on Solid Oxide Fuel Cells . 2013

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5. Self-directing organometallic deposition of ruthenium: Preparation, characterization and evaluation of bimetallic, ruthenium adatom modified platinum surfaces for the electrooxidation of methanol in direct methanol fuel cells. [D] . Lee, Christopher Edward. 2003

机译：钌的自指导有机金属沉积：直接甲醇燃料电池中甲醇电氧化的双金属，钌原子原子修饰的铂表面的制备，表征和评估。
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7. Platinum-supported mesoporous carbon (Pt/CMK-3) as anodic catalyst for direct methanol fuel cell applications: The effect of preparation and deposition methods [O] . Kuppan Balaiah, Selvam Parasuraman 2012

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8. Ink-Jet Printing of Electrolyte and Anode Functional Layer For Solid Oxide Fuel Cells (Postprint) [R] . Rottmayer, M., Reitz, T. L., Young, D., 2010

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Atomic Layer Deposition of Ruthenium on Platinum Anode for Direct Methanol Solid Oxide Fuel Cells

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